News & Updates

27

2023-12

Sodium Hydroxide Water Treatment for Pollution Control

For sodium hydroxide leaks into water, appropriate measures should be taken based on the estimated leakage amount and the characteristics of the water body. Depending on the water body’s environment and the monitored pH levels, determine whether to add acid for neutralization and, if so, how much, as well as how much water to add for dilution. Analytical Methods The determination of sodium hydroxide concentration typically uses acid-base neutralization titration, with methyl orange as the indicator. Titrate with a standard hydrochloric acid solution until the color changes from yellow to orange, indicating the endpoint. Neutralization of Sulfate-Contaminated Water Concentrated sulfuric acid should be diluted before being added. The minimum amount of sulfuric acid required to neutralize sodium hydroxide can be calculated using the formula y = 125.07x, where y is the mass of concentrated sulfuric acid to be added (98% concentration), and x is the mass of sodium hydroxide leaked (x = ωm, where ω is the mass fraction of the leaked sodium hydroxide, and m is the mass of the leaked sodium hydroxide). Neutralization of Hydrochloric Acid-Contaminated Water Concentrated hydrochloric acid should be diluted before being added. The minimum amount of hydrochloric acid required to neutralize sodium hydroxide can be calculated using the formula y = 303.77x, where y is the mass of concentrated hydrochloric acid to be added (30% concentration), and x is the actual mass of sodium hydroxide leaked (x = ωm, where ω is the mass fraction of the leaked sodium hydroxide, and m is the mass of the leaked sodium hydroxide).

2023-12-27

27

2023-12

Proper storage methods for sodium hydroxide.

1. Sodium hydroxide has a slight corrosive effect on glassware. When in contact, they form sodium silicate, causing the plunger in glass instruments to stick. Therefore, glass stoppers should not be used to contain sodium hydroxide solutions, as this may prevent the container from being opened. 2. Prolonged storage of hot sodium hydroxide solutions in glass containers can also damage the containers. 3. Sodium hydroxide should be stored in a cool, dry, and well-ventilated storage area, away from sources of ignition and heat. The storage temperature should not exceed 35°C, and the relative humidity should not exceed 80%. The packaging must be sealed to prevent moisture absorption. It should be stored separately from flammable materials and acids, and mixed storage should be avoided. The storage area should be equipped with appropriate materials to contain any leaks. Solid sodium hydroxide should be packed in 0.5 mm thick steel drums and sealed tightly, with a net weight of no more than 100 kg per drum. Alternatively, it can be packed in plastic bags or double-layered kraft paper bags, then placed in open-top or half-open-top steel drums. Glass bottles with threaded necks, glass bottles with iron caps, plastic bottles, or metal drums (cans) should be placed in ordinary wooden crates. Glass bottles with threaded necks, plastic bottles, or tin-plated thin steel drums (cans) should be placed in full-bottom pallet boxes, fiberboard boxes, or plywood boxes. Tin-plated thin steel drums (cans), metal drums (cans), plastic bottles, or metal flexible tubes should be placed in corrugated cardboard boxes. The packaging containers must be intact and sealed, with clear markings indicating "corrosive materials."

2023-12-27